Thermal Design And Optimization Bejan Pdf [TOP] Download Zip

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Thermal Design And Optimization Bejan Pdf Download Zip

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The present invention relates to an improved method for the production of urea and to a process for recovering aqueous ammonia from the same.
2. Description of the Prior Art
There has been a long-standing desire to develop a simple and economical method for the production of urea. Urea is a chemical fertilizer readily converted by micro-organisms into usable nitrogenous compounds essential for the growth of plants and other living matter. It is well known in the art that decomposition of urea by micro-organisms results in the production of ammonia. After many years of research and many proposals, only two approaches have been discovered which produce high yields of aqueous ammonia for the economical recovery thereof, and both involve handling urea under very acid conditions.
One method is the „cold-flash“ process disclosed in U.S. Pat. No. 3,636,533, issued Jan. 18, 1972 and U.S. Pat. No. 3,811,923 issued May 21, 1974, wherein the urea is contacted with aqueous phosphoric acid at a pressure of from 30 to 70 atmospheres at ambient temperature, and the aqueous ammonia so formed is recovered from the resultant pressure drop and returned to the process system. Although the „cold-flash“ process has been very successful, the method requires the handling of large volumes of highly corrosive materials, and it is not always feasible to employ such an elaborate and costly operation at every urea production facility.
A second method, that of reacting pure aqueous ammonia with an aqueous solution of urea in the presence of an aqueous solution of phosphoric acid, is disclosed in a number of patents, such as U.S. Pat. No. 3,147,155, issued Oct. 2, 1964

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